题目
7.完成下列反应,写出各步主要有机产物(立体结构只考虑顺反异构)或反应条件。-|||-(1)(CH3)2 CHCH=CH2 HCl(A)(A)-|||-PhCOOH →(A)- ({H)_(3)O}^+ →(B)-|||-CH3 (O)_(4)/(H)^+ →(C)-|||-(2)-|||-(O)_(4)/(H)_(2)O H2O (D)-|||-低温
题目解答
答案
见答案
(1)(CH3)2CHCH=CH2 HCl(A)PhCOOH (A)→(BC)(B)${{H}_{3}O}^{+}$ →(B)CH3 $KMn{O}_{4}/{H}^{+}$ (C)(2)_$KMn{O}_{4}/{H}_{2}O$ H2O -(D)低温
(1)(CH3)2CHCH=CH2 HCl(A)PhCOOH (A)→(BC)(B)${{H}_{3}O}^{+}$ →(B)CH3 $KMn{O}_{4}/{H}^{+}$ (C)(2)_$KMn{O}_{4}/{H}_{2}O$ H2O -(D)低温