题目
已知 913K 下:(CO)_2((g))+(Fe)((s))=(FeO)((s))+(CO)((g)) K_1^Theta=1.47;(H)_2(O)((g))+(Fe)((s))=(FeO)((s))+(H)_2((g)) K_2^Theta=2.38;则反应(H)_2((g))+(CO)_2((g))=(CO)((g))+(H)_2(O)((g))在913K时的K^Theta=( )。(精确到0.01)
已知 913K 下:$\text{CO}_2(\text{g})+\text{Fe}(\text{s})=\text{FeO}(\text{s})+\text{CO}(\text{g})$ $K_1^{\Theta}=1.47$; $\text{H}_2\text{O}(\text{g})+\text{Fe}(\text{s})=\text{FeO}(\text{s})+\text{H}_2(\text{g})$ $K_2^{\Theta}=2.38$; 则反应$\text{H}_2(\text{g})+\text{CO}_2(\text{g})=\text{CO}(\text{g})+\text{H}_2\text{O}(\text{g})$在913K时的$K^{\Theta}=$( )。(精确到0.01)
题目解答
答案
根据题目给出的两个反应:
1. $ \text{CO}_2 + \text{Fe} \leftrightarrow \text{FeO} + \text{CO} \quad K_1^\circ = 1.47 $
2. $ \text{H}_2\text{O} + \text{Fe} \leftrightarrow \text{FeO} + \text{H}_2 \quad K_2^\circ = 2.38 $
将反应1与反应2的逆反应相加,可得:
\[
K^\circ = \frac{K_1^\circ}{K_2^\circ} = \frac{1.47}{2.38} \approx 0.62
\]
最终结果为:
\[
K^\circ = 0.62
\]